View large format table. Values of the hard sphere diameter σ1 and the energy parameter ϵ1/k at 298.15°K and 1 atm pressure are reported for 39 liquids, polar as well as nonpolar. Structure, properties, spectra, suppliers and links for: CFC-116, 76-16-4. Fibers with polar functional groups can be dyed more easily than nonpolar fibers because polar groups will chemically bond with dye molecules. e.g., perfluoroethane or 1,1,1,2,2,2-hexafluoroethane Alcohol Nomenclature. 226 (2004) 109–120] and classical mixing rules. Polar Mixed-Solid Solute Systems in Supercritical Carbon Dioxide: Entrainer Effect and Its Influence on Solubility and Selectivity. The graph shows that the polar effect diminishes as the size of the molecule increases. Wormald, Benzene–polar fluid association. Column type Active phase I Reference Comment; Capillary: Porapack Q: 82. In a preceding project, functional forms for “short” Helmholtz energy equations of state for typical nonpolar and weakly polar fluids and for typical polar fluids were developed using simultaneous optimization. The binary interaction parameter, k ij, of 268 nonpolar mixtures were determined from the database of second cross virial coefficients containing 1728 experimental data points by fitting the second cross virial coefficients with a new correlation for pure compounds [L. Meng, Y.Y. Replacing all the hydrogens with fluorine will result in a nonpolar molecule similar to the analogous hydrocarbon. Normal alkane RI, non-polar column, custom temperature program. Hexafluoroethane C2F6 structure Molecular Formula C2F6 Average mass 138.012 Da Density 1.5±0.1 g/cm3 Boiling Point -82.3±8.0 °C at 760 mmHg Flash Point -60.9±10.4 °C Molar Fluorine in theory… (and in fact) It is a simple covalent non polar molecule like oxygen, but Fluorine is smaller and has fewer elections. ... , The heat of reaction of nitrogen trifluoride and hexafluoroethane, J. Phys. Chem., 1966, 70, 1326-1327. C.J. Duan, L. Li, Fluid Phase Equilib. An analysis of measurements of the vapour phase excess molar enthalpy of mixtures of (cyclohexane, or benzene + polar and non-polar fluids), The Journal of Chemical Thermodynamics, 10.1006/jcht.1999.0520, 32, 9, (1091-1112), (2000). Journal of Chemical & Engineering Data 2008, 53 (2) , 415-421. Because the molecular chains of PP are nonpolar and its surface is hydrophobic, the dye molecules will not bond chemically to the fibers. DOI: 10.1021/je700486g. Brooks M. Hybertson.